- Season 1 Episode 9: The Finale
After a final performance from contestants and their duet partners, the winner is announced.
- Season 1 Episode 8: Superstars' Choice
The celebrity singers choose a song that best showcases their duet partner's talent.
- Season 1 Episode 7: Favorite Standards
The stars and their duet partners perform standards.
- Season 1 Episode 6: Songs From the 2000's
The stars and their partners perform songs from this millennium.
- Season 1 Episode 5: Movie Night
The stars and their partners perform songs from their favorite movie soundtracks.
- Season 1 Episode 4: Party Songs
The celebrities perform party songs with their partners; an amateur is eliminated.
- Season 1 Episode 3: Songs That Inspire
The music superstars perform inspirational songs with their duet partners; a contestant is eliminated.
- Season 1 Episode 2: Classic Duets
The singers perform classic duets with their partners.
- Season 1 Episode 1: The Superstars Greatest Hits
The stars perform with their partners.